Journal article
Intramolecular [2 + 2] Photodimerization Achieved in the Solid State via Coordination-Driven Self-Assembly
Organic letters, Vol.17(13), pp.3233-3235
06/15/2015
DOI: 10.1021/acs.orglett.5b00527
PMID: 26079149
Abstract
An intramolecular [2 + 2] photocycloaddition is achieved in the organic solid state via self-assembly of Ag(I) ions and an endo-ditopic bipyridine. The cations aide to organize carbon–carbon double (CC) bonds attached to the bipyridine for the cycloaddition reaction. The CC bonds react regioselectively and quantitatively to afford a photoproduct with edge-sharing four-, five-, and six-membered rings. Our study demonstrates the first use of a metal–organic template to direct an intramolecular [2 + 2] photodimerization in the organic solid state.
Details
- Title: Subtitle
- Intramolecular [2 + 2] Photodimerization Achieved in the Solid State via Coordination-Driven Self-Assembly
- Creators
- Rebecca C LairdMichael A SinnwellNam P NguyenDale C SwensonS. V. Santhana MariappanLeonard R MacGillivray
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.17(13), pp.3233-3235
- Publisher
- American Chemical Society
- DOI
- 10.1021/acs.orglett.5b00527
- PMID
- 26079149
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Grant note
- DOI: 10.13039/100000078, name: Division of Materials Research, award: DMR-1408834
- Language
- English
- Date published
- 06/15/2015
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9983985868302771
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