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Intramolecular Addition of Stabilized Enolates to (η6-Arene)ruthenium Complexes: Synthesis of Ru-Coordinated Azaspirocycles
Journal article   Peer reviewed

Intramolecular Addition of Stabilized Enolates to (η6-Arene)ruthenium Complexes: Synthesis of Ru-Coordinated Azaspirocycles

F. Christopher Pigge, Shiyue Fang and Nigam P Rath
Organic letters, Vol.1(11), pp.1851-1854
12/01/1999
DOI: 10.1021/ol991123v

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Abstract

(formula presented) Stabilized enolates attached to cationic (arene)RuIICp complexes via an amide linkage were found to participate in nucleophilic aromatic addition reactions resulting in the formation of novel cyclohexadienyl-Ru azaspirocycles. Enolate addition to the activated arene ring was found to proceed with complete stereoselectivity.

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