Journal article
Inverted metal–organic frameworks: isoreticular decoration with organic anions using principles of supramolecular chemistry
Journal of coordination chemistry, Vol.74(1-3), pp.169-177
02/01/2021
DOI: 10.1080/00958972.2021.1880004
Abstract
A structural study of two-dimensional inverted metal–organic frameworks demonstrates that the interior cavities of the framework structures can be systematically modified by changing the organic anion of a Cu(II)-paddlewheel unit. Changing the anion allows modifications to the shapes and sizes of the cavities in a series of isoreticular frameworks. The construction of the frameworks is based on the application of a tetrafunctional organic cyclobutane ligand synthesized in the organic solid state.
Details
- Title: Subtitle
- Inverted metal–organic frameworks: isoreticular decoration with organic anions using principles of supramolecular chemistry
- Creators
- Claude L Mertzenich - Department of Chemistry, Luther College, Decorah, IA, USA, Department of Chemistry, University of Iowa, Iowa City, IA, USAGiannis S Papaefstathiou - Department of Chemistry, University of Iowa, Iowa City, IA, USATomislav Friščić - Department of Chemistry, University of Iowa, Iowa City, IA, USATamara D Hamilton - Department of Chemistry, University of Iowa, Iowa City, IA, USADejan-Krešimir Bučar - Department of Chemistry, University of Iowa, Iowa City, IA, USADale C Swenson - Department of Chemistry, University of Iowa, Iowa City, IA, USALeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, IA, USA
- Resource Type
- Journal article
- Publication Details
- Journal of coordination chemistry, Vol.74(1-3), pp.169-177
- DOI
- 10.1080/00958972.2021.1880004
- ISSN
- 0095-8972
- eISSN
- 1029-0389
- Grant note
- DOI: 10.13039/100003187, name: NSF, award: (LRM DMR-1708673
- Language
- English
- Date published
- 02/01/2021
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216588202771
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