Journal article
Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]
Journal of Crystallographic and Spectroscopic Research, Vol.23(10), pp.773-778
10/1993
DOI: 10.1007/BF01247239
Abstract
The complex salt, [1-MeimH]2[cis-MoO2(sal)2], 1, (1-Meim=1-methylimidazole, sal=o-C6H4(C-) (COC-)) has been prepared by reacting Mo(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4)Å, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, Dcalc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and Rw=0.041. © 1993 Plenum Publishing Corporation.
Details
- Title: Subtitle
- Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]
- Creators
- Kelly BoutilierLeonard R MacGillivrayS SubramanianMichael J Zaworotko
- Resource Type
- Journal article
- Publication Details
- Journal of Crystallographic and Spectroscopic Research, Vol.23(10), pp.773-778
- DOI
- 10.1007/BF01247239
- ISSN
- 0277-8068
- eISSN
- 1572-8854
- Language
- English
- Date published
- 10/1993
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216579102771
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