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Isolation of uranium(iii) primary phosphido complexes
Journal article   Peer reviewed

Isolation of uranium(iii) primary phosphido complexes

Diana Perales, Rina Bhowmick, Matthias Zeller, Pere Miro, Bess Vlaisavljevich and Suzanne C. Bart
Chemical communications (Cambridge, England), Vol.58(69), pp.963-9633
08/25/2022
DOI: 10.1039/d2cc02207a
PMID: 35950738

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Abstract

Low-valent uranium(iii) primary phosphido complexes supported by hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy (H-1, B-11, P-31 NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.
Physical Sciences Chemistry Chemistry, Multidisciplinary Science & Technology

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