Journal article
Ligand K-Edge XAS Studies of Metal-Phosphorus Bonds: Applications, Limitations, and Opportunities
Comments on modern chemistry. Part A, Comments on inorganic chemistry, Vol.38(2), pp.54-78
03/04/2018
DOI: 10.1080/02603594.2018.1465938
Abstract
Phosphorus K-edge X-ray absorption spectroscopy (XAS) is a highly effective experimental method for investigating metal-phosphorus bonding and electronic structure. Here, we provide a comprehensive review of P K-edge XAS studies of transition metal complexes and show how they were used to investigate a wide range of chemical phenomena, including covalent metal-ligand bonding, redox non-innocence in ligands, molecular magnetism, and luminescence. Limitations of the technique are discussed along with opportunities for future work.
Details
- Title: Subtitle
- Ligand K-Edge XAS Studies of Metal-Phosphorus Bonds: Applications, Limitations, and Opportunities
- Creators
- Courtney M Donahue - Department of Chemistry, The University of IowaScott R Daly - Department of Chemistry, The University of Iowa
- Resource Type
- Journal article
- Publication Details
- Comments on modern chemistry. Part A, Comments on inorganic chemistry, Vol.38(2), pp.54-78
- Publisher
- Taylor & Francis
- DOI
- 10.1080/02603594.2018.1465938
- ISSN
- 0260-3594
- eISSN
- 1548-9574
- Grant note
- 55989-DNI3 / American Chemical Society Petroleum Research Fund (10.13039/100006770)
- Language
- English
- Date published
- 03/04/2018
- Academic Unit
- Chemistry
- Record Identifier
- 9984216599902771
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