Journal article
Liquid-assisted vortex grinding supports the single-step solid-state construction of a [2.2]paracyclophane
Faraday discussions, Vol.170, pp.35-40
2014
DOI: 10.1039/C4FD00006D
PMID: 25407845
Abstract
We employ vortex grinding to generate a [2.2]paracyclophane in the organic solid state. The vortex grinding is aided with the addition of a small amount of liquid phase to facilitate topochemical [2 + 2] photodimerizations that generate the cyclophane stereoselectively and in up to quantitative yield. The use of the liquid phase increases the scope of the vortex method.
Details
- Title: Subtitle
- Liquid-assisted vortex grinding supports the single-step solid-state construction of a [2.2]paracyclophane
- Creators
- Jelena Stojaković - Department of Chemistry, University of Iowa, Iowa City, USABrian S Farris - Department of Chemistry, University of Iowa, Iowa City, USALeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, USA
- Resource Type
- Journal article
- Publication Details
- Faraday discussions, Vol.170, pp.35-40
- DOI
- 10.1039/C4FD00006D
- PMID
- 25407845
- ISSN
- 1359-6640
- eISSN
- 1364-5498
- Language
- English
- Date published
- 2014
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216581402771
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