Journal article
Mechanochemical activation and oxidation of U(IV)O 2
Chemical communications (Cambridge, England), Vol.58(28), pp.4528-4531
03/14/2022
DOI: 10.1039/D2CC00242F
PMID: 35302570
Abstract
Mechanochemical impact induces oxidation of U(IV)O2 in presence of alkali metal peroxides Li2O2 and Na2O2 during liquid-assisted grinding, resulting in respective alkali U(VI) triperoxide phases (e.g. Na4[UO2(O2)3]·9H2O), based on powder X-ray diffraction analysis, solid- and solution-phase vibrational spectroscopy.
Details
- Title: Subtitle
- Mechanochemical activation and oxidation of U(IV)O 2
- Creators
- Dmytro V Kravchuk - University of IowaTori Z Forbes - University of Iowa
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.58(28), pp.4528-4531
- DOI
- 10.1039/D2CC00242F
- PMID
- 35302570
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Language
- English
- Date published
- 03/14/2022
- Academic Unit
- Civil and Environmental Engineering; Chemistry
- Record Identifier
- 9984229313102771
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