Journal article
Metal-Catalyzed Allylation of Organoboranes and Organoboronic Acids
Synthesis, Vol.2010(11), pp.1745-1762
06/01/2010
DOI: 10.1055/s-0029-1218756
Abstract
Abstract Metal-catalyzed transformations have emerged as indispensable tools for carbon-carbon bond formation in contemporary synthetic chemistry. Metal-promoted cross-couplings and metal-catalyzed allylations represent two of the most widely used reaction types. However, cross-coupling reactions involving allylic electrophiles have not been extensively explored. This review presents an overview of efforts aimed at developing metal-catalyzed allylation reactions between allylic alcohol derivatives and alkenyl or aryl organoboron compounds, leading to 1,4-dienes and allylic arenes, respectively. Particular emphasis is given to regio- and stereoselective allylation procedures. 1 Introduction 2 Allylations Proceeding through π-Allyl Intermediates 2.1 Palladium Catalyzed 2.2 Nickel Catalyzed 2.3 Rhodium Catalyzed 3 Formal S N 2′-Type Allylations 3.1 Palladium Catalyzed 3.2 Rhodium Catalyzed 4 Conclusions and Future Directions
Details
- Title: Subtitle
- Metal-Catalyzed Allylation of Organoboranes and Organoboronic Acids
- Creators
- F. Christopher Pigge
- Resource Type
- Journal article
- Publication Details
- Synthesis, Vol.2010(11), pp.1745-1762
- DOI
- 10.1055/s-0029-1218756
- ISSN
- 0039-7881
- eISSN
- 1437-210X
- Language
- English
- Date published
- 06/01/2010
- Academic Unit
- Chemistry; Radiology
- Record Identifier
- 9983985848302771
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