Journal article
Metal-mediated reactivity in the organic solid state: from self-assembled complexes to metal-organic frameworks
Chemical Society reviews, Vol.36(8), pp.1239-1248
08/2007
DOI: 10.1039/b516074j
PMID: 17619684
Abstract
The purpose of this tutorial review is to address the use of metal ions to mediate reactions in the organic solid state. We describe metal complexes and coordination networks that facilitate dimerizations, oligomerizations and polymerizations of olefins and acetylenes via irradiation (e.g. ultraviolet (UV) and (60)Co gamma-rays) and thermal annealing. We show how metal ions can be utilized to direct the formation of polymers and molecules. We also describe how supramolecular chemistry has recently influenced dimerization processes in self-assembled metal-organic solids.
Details
- Title: Subtitle
- Metal-mediated reactivity in the organic solid state: from self-assembled complexes to metal-organic frameworks
- Creators
- Ivan G Georgiev - Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USALeonard R MacGillivray
- Resource Type
- Journal article
- Publication Details
- Chemical Society reviews, Vol.36(8), pp.1239-1248
- DOI
- 10.1039/b516074j
- PMID
- 17619684
- ISSN
- 0306-0012
- eISSN
- 1460-4744
- Language
- English
- Date published
- 08/2007
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216595102771
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