Journal article
Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State
ChemPlusChem (Weinheim, Germany), Vol.81(8), pp.893-898
08/2016
DOI: 10.1002/cplu.201600261
PMID: 31968836
Abstract
Trisubstituted olefins are reactants in template‐directed, solid‐state [2+2] photocycloaddition reactions. Whereas hydrogen‐bond‐based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.
Trisubstituted olefins undergo templated [2+2] photocycloaddition reactions in the solid state. Metal–organic templates result in crystalline assemblies where C=C bonds react stereoselectively and result in quantitative yield (see figure). Hydrogen‐bond‐based templates afford assemblies with olefins that are photostable.
Details
- Title: Subtitle
- Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State
- Creators
- Elizabeth Elacqua - University of IowaMichael A Sinnwell - University of IowaBradley P Loren - University of IowaPaul T Jurgens - University of IowaRyan H Groeneman - University of IowaEric W Reinheimer - California State University San MarcosLeonard R MacGillivray - University of Iowa
- Resource Type
- Journal article
- Publication Details
- ChemPlusChem (Weinheim, Germany), Vol.81(8), pp.893-898
- DOI
- 10.1002/cplu.201600261
- PMID
- 31968836
- ISSN
- 2192-6506
- eISSN
- 2192-6506
- Number of pages
- 6
- Grant note
- National Science Foundation (DMR-1408834)
- Language
- English
- Date published
- 08/2016
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216678502771
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