Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals

Kyounghoon Lee; Po-Ni Lai; Riffat Parveen; Courtney M Donahue; Mikayla M Wymore; Blake A Massman; Bess Vlaisavljevich; Thomas S Teets; Scott R Daly

doi:10.1039/D0CC03427D

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Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals

Journal article

Peer reviewed

Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals

Kyounghoon Lee, Po-Ni Lai, Riffat Parveen, Courtney M Donahue, Mikayla M Wymore, Blake A Massman, Bess Vlaisavljevich, Thomas S Teets and Scott R Daly

Chemical communications (Cambridge, England), Vol.56(64), pp.9110-9113

08/11/2020

DOI: 10.1039/D0CC03427D

PMID: 32648569

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Abstract

Here we report how reactions at a chemically reactive diphosphine shift the long-lived luminescent colour of a crystalline three-coordinate Cu(i) complex from green to blue. The results demonstrate how vapochromism and single-crystal-to-single-crystal transformations can be achieved using ligand-centered reactions.

Details

Title: Subtitle: Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals
Creators: Kyounghoon Lee - Department of Chemistry, The University of Iowa, Iowa City, USA
Po-Ni Lai - Department of Chemistry, University of Houston, Houston, USA
Riffat Parveen - Department of Chemistry, The University of South Dakota, Vermillion, USA
Courtney M Donahue - Department of Chemistry, The University of Iowa, Iowa City, USA
Mikayla M Wymore - Department of Chemistry, The University of Iowa, Iowa City, USA
Blake A Massman - Department of Chemistry, The University of Iowa, Iowa City, USA
Bess Vlaisavljevich - Department of Chemistry, The University of South Dakota, Vermillion, USA
Thomas S Teets - Department of Chemistry, University of Houston, Houston, USA
Scott R Daly - Department of Chemistry, The University of Iowa, Iowa City, USA
Resource Type: Journal article
Publication Details: Chemical communications (Cambridge, England), Vol.56(64), pp.9110-9113
DOI: 10.1039/D0CC03427D
PMID: 32648569
NLM abbreviation: Chem Commun (Camb)
ISSN: 1359-7345
eISSN: 1364-548X
Publisher: Royal Society of Chemistry
Grant note: DOI: 10.13039/100000928, name: Welch Foundation, award: E-1887; DOI: 10.13039/100000001, name: National Science Foundation, award: 1650894; DOI: 10.13039/100008893, name: University of Iowa
Language: English
Date published: 08/11/2020
Academic Unit: Chemistry
Record Identifier: 9984216717302771

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