Journal article
Modulation of Fe-Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors
Chemical communications (Cambridge, England), Vol.60(64), pp.8399-8402
07/19/2024
DOI: 10.1039/d4cc02522a
PMID: 39028006
Appears in UI Libraries Support Open Access
Abstract
Here we report the synthesis and characterization of diiron complexes containing triaryl N4 and N2S2 ligands derived from o-phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity of the flanking NMe2 and SMe donor groups.Here we report the synthesis and characterization of diiron complexes containing triaryl N4 and N2S2 ligands derived from o-phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity of the flanking NMe2 and SMe donor groups.
Details
- Title: Subtitle
- Modulation of Fe-Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors
- Creators
- Kyle D Spielvogel - University of IowaEmily J Campbell - University of IowaSabyasachi Roy Chowdhury - University of South DakotaFlorian Benner - Michigan State UniversitySelvan Demir - Michigan State UniversityGillian P Hatzis - The Ohio State UniversityHayley R Petras - University of IowaDunya Sembukuttiarachchige - University of IowaJames J Shepherd - University of IowaChristine M Thomas - The Ohio State UniversityBess Vlaisavljevich - University of IowaScott R Daly - University of Iowa
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.60(64), pp.8399-8402
- Publisher
- Royal Society of Chemistry
- DOI
- 10.1039/d4cc02522a
- PMID
- 39028006
- ISSN
- 1364-548X
- eISSN
- 1364-548X
- Language
- English
- Date published
- 07/19/2024
- Academic Unit
- Chemistry
- Record Identifier
- 9984658355202771
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