Journal article
Molecular Intermediate in the Directed Formation of a Zeolitic Metal-Organic Framework
Journal of the American Chemical Society, Vol.142(41), pp.17598-17606
10/14/2020
DOI: 10.1021/jacs.0c07862
PMID: 32957777
Abstract
Directed synthesis promises control over architecture and function of framework materials. In practice, however, designing such syntheses requires a detailed understanding of the multistep pathways of framework formations, which remain elusive. By identifying intermediate coordination complexes, this study provides insights into the complex role of a structure-directing agent (SDA) in the synthetic realization of a promising material. Specifically, a novel molecular intermediate was observed in the formation of an indium zeolitic metal-organic framework (ZMOF) with a sodalite topology. The role of the imidazole SDA was revealed by time-resolved in situ powder X-ray diffraction (XRD) and small-angle X-ray scattering (SAXS).
Details
- Title: Subtitle
- Molecular Intermediate in the Directed Formation of a Zeolitic Metal-Organic Framework
- Creators
- Michael A. Sinnwell - Pacific Northwest National LaboratoryQuin R. S. Miller - Pacific Northwest National LaboratoryLauren Palys - Oregon State UniversityDushyant Barpaga - Pacific Northwest National LaboratoryLili Liu - Pacific Northwest National LaboratoryMark E. Bowden - Environmental Molecular Sciences LaboratoryYi Han - Qingdao University of Science and TechnologySanjit Ghose - Brookhaven National LaboratoryMaria L. Sushko - Pacific Northwest National LaboratoryH. Todd Schaef - Pacific Northwest National LaboratoryWenqian Xu - Argonne National LaboratoryMay Nyman - Oregon State UniversityPraveen K. Thallapally - Pacific Northwest National Laboratory
- Resource Type
- Journal article
- Publication Details
- Journal of the American Chemical Society, Vol.142(41), pp.17598-17606
- DOI
- 10.1021/jacs.0c07862
- PMID
- 32957777
- NLM abbreviation
- J Am Chem Soc
- ISSN
- 0002-7863
- eISSN
- 1520-5126
- Publisher
- Amer Chemical Soc
- Number of pages
- 9
- Grant note
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division through its Geosciences program at PNNL; United States Department of Energy (DOE) DE SC0010802 / U.S. Department of Energy, Office of Science, Basic Energy Sciences; United States Department of Energy (DOE) KC020105-FWP12152 / U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division; United States Department of Energy (DOE) DE-AC05-76RL01830 / U.S. Department of Energy; United States Department of Energy (DOE) Department of Energy's Office of Biological and Environmental Research; United States Department of Energy (DOE) DE-AC02-06CH11357; DE-SC0012704 / DOE Office of Science; United States Department of Energy (DOE)
- Language
- English
- Date published
- 10/14/2020
- Academic Unit
- Chemistry
- Record Identifier
- 9984936617902771
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