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Organic nanocrystals of [2.2]paracyclophanes achieved via sonochemistry: enhanced and red-shifted emission involving edge-to-face chromophores
Journal article   Peer reviewed

Organic nanocrystals of [2.2]paracyclophanes achieved via sonochemistry: enhanced and red-shifted emission involving edge-to-face chromophores

Elizabeth Elacqua, Paul T Jurgens, Jonas Baltrusaitis and Leonard R MacGillivray
CrystEngComm, Vol.14(22), pp.7567-7571
2012
DOI: 10.1039/c2ce26000j

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Abstract

We have prepared organic nanocrystals of [2.2]paracyclophane (pCp) and tetrakis(4-pyridylcyclobutyl)[2.2]paracyclophane (tpcp) via sonochemistry. Both nanocrystals exhibit an enhanced fluorescence compared to dilute solution, while the tpcp nanocrystals also demonstrate a red-shifted fluorescence.

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