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Physicochemical Characterization of Simulated Welding Fumes from a Spark Discharge System
Journal article   Peer reviewed

Physicochemical Characterization of Simulated Welding Fumes from a Spark Discharge System

Jae Hong Park, Imali A Mudunkotuwa, Jong Sung Kim, Aditya Stanam, Peter S Thorne, Vicki H Grassian and Thomas M Peters
Aerosol science and technology, Vol.48(7), pp.768-776
07/03/2014
DOI: 10.1080/02786826.2014.925536
PMID: 25097299
url
https://www.ncbi.nlm.nih.gov/pmc/articles/4119574View
Open Access

Abstract

This study introduces a spark discharge system (SDS) as a way to simulate welding fumes. The SDS was developed using welding rods as electrodes with an optional coagulation chamber. The size, morphology, composition, and concentration of the fume produced and the concentration of ozone (O 3 ) and nitrogen oxides (NO X ) were characterized. The number median diameter (NMD) and total number concentration (TNC) of fresh fume particles were ranged 10-23 nm and 3.1×10 7 − 6×10 7 particles/cm 3 , respectively. For fresh fume particles, the total mass concentration (TMC) measured gravimetrically ranged 85-760 μg/m 3 . The size distribution was stable over a period of 12 h. The NMD and TNC of aged fume particles were ranged 81-154 nm and 1.5×10 6 −2.7×10 6 particles/cm 3 , respectively. The composition of the aged fume particles was dominated by Fe and O with an estimated stoichiometry between that of Fe 2 O 3 and Fe 3 O 4 . Concentrations of O 3 and NO X were ranged 0.07-2.2 ppm and 1-20 ppm, respectively. These results indicate that the SDS is capable of producing stable fumes over a long-period that are similar to actual welding fumes. This system may be useful in toxicological studies and evaluation of instrumentation. Copyright 2014 American Association for Aerosol Research

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