Journal article
Potential dependence of the structure of water at the hydrophobic liquid interface
Journal of electroanalytical chemistry (Lausanne, Switzerland), Vol.609(2), pp.94-98
2007
DOI: 10.1016/j.jelechem.2007.06.016
Abstract
Potential dependant infrared visible sum frequency generation spectroscopy (SFG) spectra of the aqueous/alkanethiol interface in the OH stretching region are presented. Spectra have been mathematically fit to extract information used to elucidate the structure and conformation of H 2O at these electrochemical interfaces and the existence of a ‘flip–flop’ model for water in these environments is investigated. Comparison to recent work on Ag(1 1 1)/aqueous interface and other works on hydrophobic/aqueous interfaces corroborates assignments of OH bands in the 3800–2800 cm −1 region.
Details
- Title: Subtitle
- Potential dependence of the structure of water at the hydrophobic liquid interface
- Creators
- Scott K ShawAndrew A Gewirth
- Resource Type
- Journal article
- Publication Details
- Journal of electroanalytical chemistry (Lausanne, Switzerland), Vol.609(2), pp.94-98
- Publisher
- Elsevier B.V
- DOI
- 10.1016/j.jelechem.2007.06.016
- ISSN
- 1572-6657
- eISSN
- 1873-2569
- Language
- English
- Date published
- 2007
- Academic Unit
- Chemistry
- Record Identifier
- 9983985997302771
Metrics
15 Record Views