Journal article
Quasi self-inclusion of a 1-D coordination polymer within a 2-D hydrogen-bonded grid: a chaperone effect
Journal of coordination chemistry, Vol.74(1-3), pp.162-168
01/20/2021
DOI: 10.1080/00958972.2021.1879383
Abstract
The one-dimensional (1-D) coordination polymer [Ni(bdc)(pico)
2
(H
2
O)
2
] (where bdc = terephthalate, pico = 4-picoline) is hosted within a two-dimensional (2-D) hydrogen-bonded grid [Ni(bdc)(pico)
2
(H
2
O)
2
]·(pyz) (where pyz = pyrazine). Both coordination polymers are comprised of the same components and differ only by their hydrogen-bonding patterns. The polymers of the 2-D grids engage in O-H···N hydrogen bonds to the included pyz. The grid contains rhombohedral cavities that lie along the crystallographic ac-plane. The grids self-assemble by C-H···π interactions involving the methyl group of pico and the aromatic ring of the bdc anion. The included polymer interacts with the 2-D grids via O-H···O hydrogen bonds involving coordinated water and the bdc anion.
Details
- Title: Subtitle
- Quasi self-inclusion of a 1-D coordination polymer within a 2-D hydrogen-bonded grid: a chaperone effect
- Creators
- Ryan H Groeneman - Department of Biological Sciences, Webster UniversityDejan-Krešimir Bučar - Department of Chemistry, University College LondonLeonard R MacGillivray - Department of Chemistry, University of IowaJerry L Atwood - Department of Chemistry, University of Missouri-Columbia
- Resource Type
- Journal article
- Publication Details
- Journal of coordination chemistry, Vol.74(1-3), pp.162-168
- Publisher
- Taylor & Francis
- DOI
- 10.1080/00958972.2021.1879383
- ISSN
- 0095-8972
- eISSN
- 1029-0389
- Language
- English
- Date published
- 01/20/2021
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216576302771
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