Journal article
Rapid, facile synthesis of nitrogen-rich carbon nitride powders
Journal of Materials Chemistry, Vol.12(8), pp.2463-2469
07/26/2002
DOI: 10.1039/b109700h
Abstract
There is increasing interest in high surface area carbon nitride materials as potential coordinatively active analogs of amorphous carbon systems. It is generally difficult to produce extended carbon structures with high nitrogen contents. This article describes a facile molecular decomposition process that produces bulk quantities of an amorphous nitrogen-rich carbon nitride material, C
3
N
4+
x
where 0.5 <
x
< 0.8, in only a few seconds without the use of complex experimental apparatus. The trichloromelamine molecular precursor [(C
3
N
3
)(NHCl)
3
] rapidly decomposes when heated externally above 185 °C or when brought into contact with a heated filament. Morphological studies show that the rapid synthesis process produces a porous, sponge-like material containing spherical nanofeatures (<300 nm). These amorphous carbon nitrides were analyzed by IR, NMR, optical, and X-ray photoelectron spectroscopy, which indicate that the carbon centers have primarily sp
2
hybridization, triazine (C
3
N
3
) rings are retained in the product, and nitrogen species bridge triazines. These C
3
N
4+
x
materials are also luminescent in the blue region even after annealing to 400 °C. They exhibit thermal and chemical stability with no significant decomposition until 600 °C or reactivity with concentrated aqueous base.
Details
- Title: Subtitle
- Rapid, facile synthesis of nitrogen-rich carbon nitride powders
- Creators
- Dale R MillerJianjun WangEdward G Gillan
- Resource Type
- Journal article
- Publication Details
- Journal of Materials Chemistry, Vol.12(8), pp.2463-2469
- DOI
- 10.1039/b109700h
- ISSN
- 0959-9428
- eISSN
- 1364-5501
- Number of pages
- 7
- Date published
- 07/26/2002
- Academic Unit
- Chemistry
- Record Identifier
- 9984001169602771
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