Journal article
Reductive activation of neptunyl and plutonyl oxo species with a hydroxypyridinone chelating ligand
Chemical communications (Cambridge, England), Vol.54(76), pp.10698-10701
2018
DOI: 10.1039/C8CC05626A
PMID: 30187044
Abstract
Oxo group activation with reduction of neptunyl(vi) and plutonyl(vi) to tetravalent hydroxo species by the hydroxypyridinone siderophore derivative 3,4,3-LI-(1,2-HOPO) was investigated in the gas-phase via electrospray ionization mass spectrometry, in solution via Raman spectroscopy, and computationally via density functional theory. Dissociation of the gas-phase tetravalent complexes resulted in actinide-hydroxo bond cleavage.
Details
- Title: Subtitle
- Reductive activation of neptunyl and plutonyl oxo species with a hydroxypyridinone chelating ligand
- Creators
- Korey P CarterJiwen JianMikaela M PyrchTori Z ForbesTeresa M EatonRebecca J AbergelWibe A De JongJohn K Gibson
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.54(76), pp.10698-10701
- DOI
- 10.1039/C8CC05626A
- PMID
- 30187044
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1364-548X
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Grant note
- DOI: 10.13039/100006151, name: Basic Energy Sciences, award: DE-AC02-05CH1123, DE-SC0013980
- Language
- English
- Date published
- 2018
- Academic Unit
- Civil and Environmental Engineering; Chemistry
- Record Identifier
- 9983985962702771
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