Journal article
Resorcinol-Templated Head-to-Head Photodimerization of a Thiophene in the Solid State and Unusual Edge-to-Face Stacking in a Discrete Hydrogen-Bonded Assembly
Organic letters, Vol.16(4), pp.1052-1055
02/21/2014
DOI: 10.1021/ol4035403
PMID: 24499324
Abstract
A head-to-head photodimerization of a β-substituted thiophene stacked face-to-face in the solid state using a ditopic hydrogen-bond-donor template is reported. The face-to-face stacking is attributed to contributions of intertemplate forces, which contrasts an assembly wherein the same thiophenes stack edge-to-face yet maintain a discrete hydrogen-bonded structure. © 2014 American Chemical Society.
Details
- Title: Subtitle
- Resorcinol-Templated Head-to-Head Photodimerization of a Thiophene in the Solid State and Unusual Edge-to-Face Stacking in a Discrete Hydrogen-Bonded Assembly
- Creators
- Kristin M Hutchins - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, United StatesJoseph C Sumrak - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, United StatesLeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, United States
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.16(4), pp.1052-1055
- DOI
- 10.1021/ol4035403
- PMID
- 24499324
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Language
- English
- Date published
- 02/21/2014
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216668302771
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