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Resorcinol-Templated Synthesis of a Cofacial Terpyridine in Crystalline π-Stacked Columns
Journal article   Peer reviewed

Resorcinol-Templated Synthesis of a Cofacial Terpyridine in Crystalline π-Stacked Columns

Saikat Dutta, Dejan-Krešimir Bučar and Leonard R MacGillivray
Organic letters, Vol.13(9), pp.2260-2262
05/06/2011
DOI: 10.1021/ol200532t
PMID: 21488677

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Abstract

Chemical equations presented. A resorcinol achieves a templated stereospecific and near-quantitative synthesis of a cofacial terpyridine in the solid state. The solid-state synthesis occurs in one-dimensional π-stacked columns with reactivities highly sensitive to peripheral groups attached to the template. © 2011 American Chemical Society.

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