Journal article
Rhenium tricarbonyl complexes of AIE active tetraarylethylene ligands: tuning luminescence properties and HSA-specific binding
Dalton transactions : an international journal of inorganic chemistry, Vol.46(43), pp.15040-15047
2017
DOI: 10.1039/C7DT03380J
PMID: 29063077
Abstract
The synthesis and photophysical properties of luminescent Re(i) tricarbonyl complexes prepared from bis(pyridyl)- and bis(quinolyl) tetraarylethylene (TAE) ligands are reported. Emission wavelengths of the complexes are influenced by structural variation in the tetraarylethylene ligands, and several complexes display aggregation-induced enhanced emission in aqueous solution. A Re(i) complex prepared from an indole-functionalized TAE ligand shows significant enhancement in its luminescence intensity accompanied by a remarkable blue shift (∼95 nm) upon specific binding to site II of human serum albumin.
Details
- Title: Subtitle
- Rhenium tricarbonyl complexes of AIE active tetraarylethylene ligands: tuning luminescence properties and HSA-specific binding
- Creators
- Moustafa T Gabr - Department of Chemistry, University of Iowa, Iowa City, USAF. Christopher Pigge - Department of Chemistry, University of Iowa, Iowa City, USA
- Resource Type
- Journal article
- Publication Details
- Dalton transactions : an international journal of inorganic chemistry, Vol.46(43), pp.15040-15047
- DOI
- 10.1039/C7DT03380J
- PMID
- 29063077
- ISSN
- 1477-9226
- eISSN
- 1477-9234
- Language
- English
- Date published
- 2017
- Academic Unit
- Radiology; Chemistry
- Record Identifier
- 9984216586202771
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