Rhodium-catalyzed redox allylation reactions of ketones

Florence J Williams; Robin E Grote; Elizabeth R Jarvo

doi:10.1039/c1cc14691b

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Rhodium-catalyzed redox allylation reactions of ketones

Journal article

Peer reviewed

Rhodium-catalyzed redox allylation reactions of ketones

Florence J Williams, Robin E Grote and Elizabeth R Jarvo

Chemical communications (Cambridge, England), Vol.48(10), pp.1496-1498

02/01/2012

DOI: 10.1039/c1cc14691b

PMID: 21984365

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Abstract

Ketones react with allyl acetate to generate tertiary homoallylic alcohols in the presence of a rhodium catalyst and bis(pinacolato)diboron. A range of substrates, including aryl, alkyl and cyclic ketones react smoothly under these conditions. Diastereoselective allylation reactions of functionalized ketones such as pregnenolone acetate are also reported.

Propanols - chemistry

Oxidation-Reduction

Stereoisomerism

Allyl Compounds - chemistry

Ketones - chemistry

Acetates - chemistry

Organometallic Compounds - chemistry

Molecular Structure

Catalysis

Alkylation

Propanols - chemical synthesis

Rhodium - chemistry

Details

Title: Subtitle: Rhodium-catalyzed redox allylation reactions of ketones
Creators: Florence J Williams - Natural Sciences I 4114, Department of Chemistry, University of California, Irvine, Irvine, California, USA
Robin E Grote
Elizabeth R Jarvo
Resource Type: Journal article
Publication Details: Chemical communications (Cambridge, England), Vol.48(10), pp.1496-1498
DOI: 10.1039/c1cc14691b
PMID: 21984365
NLM abbreviation: Chem Commun (Camb)
ISSN: 1359-7345
eISSN: 1364-548X
Publisher: Royal Society of Chemistry; England
Language: English
Date published: 02/01/2012
Academic Unit: Iowa Neuroscience Institute; Chemistry
Record Identifier: 9984065373302771

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