Journal article
Selective [2+2+2] Cycloaddition of Nickel-Benzyne and an Asymmetric 1,3-Diyne: An Iterative Route to Substituted [n]Acenes
Synthesis (Stuttgart), Vol.2004(18), pp.3084-3088
12/17/2004
DOI: 10.1055/s-2004-834894
Abstract
Abstract
A new iterative route to substituted acenes is reported that centers on regioselective cycloaddition of a nickel-benzyne and 1-trimethylsilyl-1,3-pentadiyne. The five-step sequence installs two fused aromatic rings and two methyl substituents onto the backbone in 27% overall yield.
Details
- Title: Subtitle
- Selective [2+2+2] Cycloaddition of Nickel-Benzyne and an Asymmetric 1,3-Diyne: An Iterative Route to Substituted [n]Acenes
- Creators
- Kimberly R. DeatonChristopher S. StrouseMary S. Gin
- Resource Type
- Journal article
- Publication Details
- Synthesis (Stuttgart), Vol.2004(18), pp.3084-3088
- DOI
- 10.1055/s-2004-834894
- ISSN
- 0039-7881
- eISSN
- 1437-210X
- Language
- English
- Date published
- 12/17/2004
- Academic Unit
- Hematology, Oncology, and Blood & Marrow Transplantation; Internal Medicine
- Record Identifier
- 9984359791602771
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