Journal article
Sequential Reactions with Grubbs Catalyst and AD-mix-α/β Using PDMS Thimbles
Organic letters, Vol.11(1), pp.33-36
01/01/2009
DOI: 10.1021/ol8022215
PMID: 19055321
Abstract
Incompatible Grubbs catalyst and an osmium dihydroxylation catalyst were site-isolated from each other using polydimethylsiloxane thimbles. The Grubbs catalyst was added to the interior of the thimbles, and AD-mix-α//β was added to the exterior. Organic substrates readily fluxed through the walls of the thimbles and reacted with each catalyst. A series of cascade reactions were developed including those with intermediates possessing low boiling points or that were foul smelling. © 2009 American Chemical Society.
Details
- Title: Subtitle
- Sequential Reactions with Grubbs Catalyst and AD-mix-α/β Using PDMS Thimbles
- Creators
- Martin T Mwangi - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242Michael D Schulz - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242Ned B Bowden - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.11(1), pp.33-36
- DOI
- 10.1021/ol8022215
- PMID
- 19055321
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Language
- English
- Date published
- 01/01/2009
- Academic Unit
- Chemistry
- Record Identifier
- 9984216595902771
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