Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(μ3-O)8(μ3-OR)65+ (R = H, Et)

John H Thurston; Dale C Swenson; Louis Messerle

doi:10.1039/b504864h

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Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(μ3-O)8(μ3-OR)65+ (R = H, Et)

Journal article

Peer reviewed

Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(μ3-O)8(μ3-OR)65+ (R = H, Et)

John H Thurston, Dale C Swenson and Louis Messerle

Chemical communications (Cambridge, England), Vol.2005(33), pp.4228-4230

2005

DOI: 10.1039/b504864h

PMID: 16100612

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Abstract

Base hydrolysis of BiO(ClO4) yields ClO4− salts of the novel nonabismuth polyoxo cation Bi9(μ3-O)8(μ3-OH)65+ (1); ethanolysis converts 1 to the ethoxide Bi9(μ3-O)8(μ3-OEt)65+ (2).

Details

Title: Subtitle: Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(μ3-O)8(μ3-OR)65+ (R = H, Et)
Creators: John H Thurston
Dale C Swenson
Louis Messerle
Resource Type: Journal article
Publication Details: Chemical communications (Cambridge, England), Vol.2005(33), pp.4228-4230
DOI: 10.1039/b504864h
PMID: 16100612
NLM abbreviation: Chem Commun (Camb)
ISSN: 1359-7345
eISSN: 1364-548X
Publisher: Royal Society of Chemistry
Language: English
Date published: 2005
Academic Unit: Radiology; Chemistry
Record Identifier: 9983985944102771

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