Journal article
Stereochemistry of the side-chain dehydrogenation of N-benzyloxycarbonyl-(S)-tryptophan by Chromobacterium violaceum
Journal of the Chemical Society, Chemical Communications, Vol.1977(23), pp.842-843
1977
DOI: 10.1039/C39770000842
Abstract
Using N-benzyloxycarbonyl-(2S,3R)- and -(2S, 3S)-[3-14C, 3-3H]tryptophan it was shown that the side-chain dehydrogenation of N-benzyloxycarbonyltryptophan by Chromobacterium violaceum involves a syn elimination of the hydrogens from C-2 and C-3 to give N-benzyloxycarbonyl-2,3-dehydrotryptophan of Z configuration.
Details
- Title: Subtitle
- Stereochemistry of the side-chain dehydrogenation of N-benzyloxycarbonyl-(S)-tryptophan by Chromobacterium violaceum
- Creators
- Mark E Gustafson - University of IowaDelwyn Miller - University of IowaPatrick J Davis - College of PharmacyJohn P Rosazza - University of IowaChing-Jer Chang - Purdue University West LafayetteHeinz G Floss - Purdue University West Lafayette
- Resource Type
- Journal article
- Publication Details
- Journal of the Chemical Society, Chemical Communications, Vol.1977(23), pp.842-843
- DOI
- 10.1039/C39770000842
- ISSN
- 0022-4936
- Number of pages
- 2
- Date published
- 1977
- Academic Unit
- Psychiatry; Pharmacy
- Record Identifier
- 9984280880202771
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