Journal article
Stereospecific and quantitative photodimerisation of terminal olefins in the solid state
Chemical communications (Cambridge, England), Vol.46(27), pp.4956-4958
07/21/2010
DOI: 10.1039/c0cc01184c
PMID: 20517572
Abstract
Reaction of 4-vinylpyridine with AgClO(3) yields a crystalline solid that supports a stereospecific and quantitative [2+2] photodimerisation of two terminal olefins. Structural dynamics of the -CH[double bond, length as m-dash]CH(2) group, nature of the counterion, and extended packing influence the photoreactivity.
Details
- Title: Subtitle
- Stereospecific and quantitative photodimerisation of terminal olefins in the solid state
- Creators
- Ivan G Georgiev - Department of Chemistry, University of Iowa, Iowa City, IA, USADejan-Kresimir BucarLeonard R Macgillivray
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.46(27), pp.4956-4958
- DOI
- 10.1039/c0cc01184c
- PMID
- 20517572
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Language
- English
- Date published
- 07/21/2010
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216718202771
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