Journal article
Structural consequences of M-Cl…H-N hydrogen bonds in substituted pyridinium salts of the cobalt(II)tetrachloride anion isolated from liquid clathrate media
Supramolecular chemistry, Vol.7(2), pp.167-169
05/01/1996
DOI: 10.1080/10610279608035193
Abstract
The crystal and molecular structures of two substituted pyridinium salts of the cobalt(II)tetrachloride anion, [4-picolinium]2[CoCl4] 1 and [4,4′-Bipyridinium][CoCl4] 2, isolated from liquid clathrate media are reported in order to gain an understanding into the preferred orientation adopted by such interacting moieties. We demonstrate that M-Cl⋯H-N hydrogen bonds principally govern the solid-state self-assembly of these systems. Furthermore, we reveal that 1 possesses the first noted example of a dimeric three-center hydrogen bond.
Details
- Title: Subtitle
- Structural consequences of M-Cl…H-N hydrogen bonds in substituted pyridinium salts of the cobalt(II)tetrachloride anion isolated from liquid clathrate media
- Creators
- Leonard J Barbour - a Department of Chemistry , University of Missouri-Columbia , Columbia, Missouri, 65211, USALeonard R Macgillivray - a Department of Chemistry , University of Missouri-Columbia , Columbia, Missouri, 65211, USAJerry L Atwood
- Resource Type
- Journal article
- Publication Details
- Supramolecular chemistry, Vol.7(2), pp.167-169
- DOI
- 10.1080/10610279608035193
- ISSN
- 1061-0278
- eISSN
- 1029-0478
- Language
- English
- Date published
- 05/01/1996
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216723202771
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