Journal article
Structural consequences of competing noncovalent forces: the out–out conformation of the doubly protonated [2.2.2]cryptand
Chemical communications (Cambridge, England), Vol.1997(5), pp.477-478
1997
DOI: 10.1039/a608603i
Abstract
The reaction of [2.2.2]cryptand 1 with 2,6-dihydroxybenzoic acid (dhbH) in toluene affords the complex [1-2H]- [(2,6-dhb) 2 ]; its crystal structure exhibits the first solid state evidence of the out–out form of the doubly protonated macrobicycle and illustrates the role of C–H···O hydrogen bonds in providing additional stability to the cavity of the ligand.
Details
- Title: Subtitle
- Structural consequences of competing noncovalent forces: the out–out conformation of the doubly protonated [2.2.2]cryptand
- Creators
- Leonard R MacGillivrayJerry L Atwood
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.1997(5), pp.477-478
- DOI
- 10.1039/a608603i
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Language
- English
- Date published
- 1997
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216599802771
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