Journal article
Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π−–π stacking
Chemical communications (Cambridge, England), Vol.56(49), pp.6708-6710
05/18/2020
DOI: 10.1039/d0cc02671a
PMID: 32420555
Abstract
Salt cocrystals with components that assemble by hydrogen bonds and aromatic anion–molecule stacks (π−–π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and 10-component aggregates with components in double and quadruple face-to-face stacks. DFT calculations support the π−–π stacks to help stabilize the salt cocrystals.
Details
- Title: Subtitle
- Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π−–π stacking
- Creators
- Shweta P YelgaonkarDaniyal Kiani - Department of Chemical and Biomolecular Engineering, Lehigh University, B336 Iacocca Hall, 111 Research Drive, Bethlehem, Pennsylvania 18015, USAJonas Baltrusaitis - Department of Chemical and Biomolecular Engineering, Lehigh University, B336 Iacocca Hall, 111 Research Drive, Bethlehem, Pennsylvania 18015, USALeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, IA 52242, USA. len-macgillivray@uiowa.edu
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.56(49), pp.6708-6710
- DOI
- 10.1039/d0cc02671a
- PMID
- 32420555
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Grant note
- DOI: 10.13039/100000086, name: Directorate for Mathematical and Physical Sciences, award: DMR-1708673
- Language
- English
- Date published
- 05/18/2020
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216606902771
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