Journal article
Suzuki and Heck coupling reactions mediated by palladium complexes bearing trans-spanning diphosphines
Journal of Organometallic Chemistry, Vol.690(2), pp.477-481
2005
DOI: 10.1016/j.jorganchem.2004.09.077
Abstract
Suzuki and Heck coupling reactions mediated by palladium complexes bearing trans-spanning diphosphines Palladium complexes of three trans-spanning diphosphines are examined for effecting C–C coupling reactions. Ten aryl halides of varying electron density were screened in Suzuki coupling reactions with phenylboronic acid and in Heck reactions with styrene. Palladium complexes of three trans-spanning diphosphines are examined for effecting C–C coupling reactions. Ten aryl halides of varying electron density were screened in Suzuki coupling reactions with phenylboronic acid and in Heck reactions with styrene. The results are discussed in terms of the unique flexibility and shape of the meta-terphenyl backbone upon which the diphosphine ligand is built.
Details
- Title: Subtitle
- Suzuki and Heck coupling reactions mediated by palladium complexes bearing trans-spanning diphosphines
- Creators
- Rhett C SmithChristina R BodnerMeredith J EarlNathaniel C SearsNicholas E HillLee M BishopNicholas SizemoreDave T HehemannJustin J BohnJohn D Protasiewicz
- Resource Type
- Journal article
- Publication Details
- Journal of Organometallic Chemistry, Vol.690(2), pp.477-481
- Publisher
- Elsevier B.V
- DOI
- 10.1016/j.jorganchem.2004.09.077
- ISSN
- 0022-328X
- eISSN
- 1872-8561
- Language
- English
- Date published
- 2005
- Academic Unit
- Ophthalmology and Visual Sciences
- Record Identifier
- 9983979922302771
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