Journal article
Syntheses and structures of W2(µ-Cl)3Cl6– and W2(µ-Cl)2Cl82–, new d2–d2 confacial and edge-sharing bioctahedral ditungsten compounds, and a convenient synthesis of W2(µ-Cl)3Cl62–
Chemical communications (Cambridge, England), Vol.1998(19), pp.2137-2138
1998
DOI: 10.1039/a803903h
Abstract
(NR4)W2Cl9 and (NR4)2W2Cl10, prepared by addition of NR4Cl (R = alkyl) to (WCl4)x powder in CH2Cl2, have confacial [W=W, 2.689(1) Å] and edge-sharing bioctahedral [W=W, 2.792(1) Å] structures, respectively, as NBnEt3+ salts, and convert with added NR4Cl to (NR4)2W2Cl9 and (NR4)WCl6 and eventually (NR4)2WCl6; (NR4)W2Cl9 can be converted to (NR4)2W2Cl10 by NR4Cl at -30 °C.
Details
- Title: Subtitle
- Syntheses and structures of W2(µ-Cl)3Cl6– and W2(µ-Cl)2Cl82–, new d2–d2 confacial and edge-sharing bioctahedral ditungsten compounds, and a convenient synthesis of W2(µ-Cl)3Cl62–
- Creators
- Vladimir KolesnichenkoDale C SwensonLouis Messerle
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.1998(19), pp.2137-2138
- DOI
- 10.1039/a803903h
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Language
- English
- Date published
- 1998
- Academic Unit
- Radiology; Chemistry
- Record Identifier
- 9984216712702771
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