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Synthesis and pulse radiolytic studies of mono- and polyfluorinated biphenyls
Journal article   Peer reviewed

Synthesis and pulse radiolytic studies of mono- and polyfluorinated biphenyls

Elke Anklam, Klaus-Dieter Asmus and Larry W. Robertson
Journal of fluorine chemistry, Vol.38(2), pp.209-216
1988
DOI: 10.1016/S0022-1139(00)83030-4

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Abstract

The polyfluorinated biphenyls investigated were synthesized by reaction of fluorinated anilines with excess benzene and characterized by spectroscopic methods. Upon pulse radiolysis of the polyfluorinated biphenyls in dichloroethane radical cations are formed. By comparison with unsubstituted biphenyl the fluoro-substitution does not exert a strong effect on the optical absorption spectra or the first half-lives of the biphenyl radical cations.

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