Journal article
Synthesis and structural characterization of a Cu(I) dimer of a tris(oxazoline) ligand
Inorganica Chimica Acta, Vol.210(1), pp.87-90
1993
DOI: 10.1016/S0020-1693(00)82827-3
Abstract
The synthesis of a new tripodal tris(oxazoline) ligand, tris[4,4-dimethyl-2-(4,5-dihydrooxazolyl)]methylamine is described, and details of the X-ray crystal_structure of its Cu(I) complex are presented. The complex crystallizes as a dimer in the triclinic space group
P
1
. Each Cu(I) ion is coordinated in a distorted trigonal geometry by two oxazoline groups from one tripod and a third oxazoline from the second ligand. The Cu(I)-Cu(I) distance is 5.7 Å. The CO adduct of the complex exhibits ν(CO)= 2066 cm
−1.
Details
- Title: Subtitle
- Synthesis and structural characterization of a Cu(I) dimer of a tris(oxazoline) ligand
- Creators
- Thomas N SorrellF.Christopher PiggePeter S White
- Resource Type
- Journal article
- Publication Details
- Inorganica Chimica Acta, Vol.210(1), pp.87-90
- Publisher
- Elsevier B.V
- DOI
- 10.1016/S0020-1693(00)82827-3
- ISSN
- 0020-1693
- eISSN
- 1873-3255
- Language
- English
- Date published
- 1993
- Academic Unit
- Radiology; Chemistry
- Record Identifier
- 9984216604302771
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