Journal article
Synthesis and structure of (H2O)(12-crown-4)-Co(II)(Co(II)Cl3)(μ-Cl) isolated from a liquid clathrate medium
Journal of chemical crystallography, Vol.27(8), pp.453-456
08/1997
DOI: 10.1007/BF02576583
Abstract
The crystal structure of (H2O)(12-crown-4)Co(II)(Co(II)Cl3)(μ-Cl)1 is reported. Crystal data for1: monoclinic, space groupP2
1/m, a=7.958(8) Å,b=12.006(1) Å,c=69.017(9) Å, β=107.896(2)0, Dc=1.84 g cm−3,Z=2,R1=0.025,wR2=0.059. The crown ether acts as a tetradentate ligand and partially completes the binding sphere of the Co(II) ion which also includes one water oxygen atom and a bridging chloride ligand, the latter of which may be regarded to originate from a [CoCl4]2− ion.
Details
- Title: Subtitle
- Synthesis and structure of (H2O)(12-crown-4)-Co(II)(Co(II)Cl3)(μ-Cl) isolated from a liquid clathrate medium
- Creators
- Leonard MacGillivray - Department of Chemistry University of Missouri-Columbia 65211 Columbia MissouriJerry Atwood - Department of Chemistry University of Missouri-Columbia 65211 Columbia Missouri
- Resource Type
- Journal article
- Publication Details
- Journal of chemical crystallography, Vol.27(8), pp.453-456
- Publisher
- Kluwer Academic Publishers-Plenum Publishers
- DOI
- 10.1007/BF02576583
- ISSN
- 1074-1542
- eISSN
- 1572-8854
- Language
- English
- Date published
- 08/1997
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216710202771
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