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Synthesis of ThCr2Si2-type arsenides from Bi flux
Journal article   Peer reviewed

Synthesis of ThCr2Si2-type arsenides from Bi flux

Corey M. Thompson, Kirill Kovnir, Stephanie Eveland, Mitchell J. Herring and Michael Shatruk
Chemical communications (Cambridge, England), Vol.47(19), pp.5563-5565
04/26/2011
DOI: 10.1039/c1cc10578g
PMID: 21483911

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Abstract

LaCo2As2 can be synthesized as pure crystalline material by annealing a mixture of elements in Bi flux. The reaction, however, is accompanied by the incorporation of a small quantity of Bi into the structure and the formation of vacancies in the Co sublattice, which lead to substantial changes in structural and magnetic properties of the material.
Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology

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