Journal article
Synthesis of dialkyl and diaryl benzylphosphonates through a ZnI2-mediated reaction
Tetrahedron letters, Vol.53(49), pp.6682-6684
12/05/2012
DOI: 10.1016/j.tetlet.2012.09.114
Abstract
Several trialkyl and two triaryl phosphites have been tested for their reactivity in the zinc iodide mediated conversion of benzyl alcohol to the corresponding phosphonates. Most react smoothly to afford the desired phosphonate diesters, including hindered and nonracemic phosphites. The implications of this reactivity on the reactions involved in the transformation are discussed.
Details
- Title: Subtitle
- Synthesis of dialkyl and diaryl benzylphosphonates through a ZnI2-mediated reaction
- Creators
- Rebekah M RichardsonRocky J BarneyDavid F Wiemer
- Resource Type
- Journal article
- Publication Details
- Tetrahedron letters, Vol.53(49), pp.6682-6684
- Publisher
- Elsevier Ltd
- DOI
- 10.1016/j.tetlet.2012.09.114
- ISSN
- 0040-4039
- eISSN
- 1873-3581
- Language
- English
- Date published
- 12/05/2012
- Academic Unit
- Chemistry; Neuroscience and Pharmacology
- Record Identifier
- 9983985820202771
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