Journal article
Synthesis of optically active methylcyclopentanoids: intermediates for the assembly of complex diterpenoids
Journal of organic chemistry, Vol.55(21), pp.5613-5619
10/01/1990
DOI: 10.1021/jo00308a020
Abstract
A large number of diterpenoids can be classified as 4-methylcyclopentanoid derivatives, including compounds with the jatrophane, lathyrane, and tigliane (phorbol) skeletons. Three synthetic routes to 4-methylcyclopentanoids have been developed to obtain chiral, nonracemic synthons for assembly of the diterpenoids. These routes draw on the readily available monoterpenoids citronellol or pulegone as chiral resources, providing for synthesis of natural diterpenoid enantiomers without recourse to resolution. © 1990, American Chemical Society. All rights reserved.
Details
- Title: Subtitle
- Synthesis of optically active methylcyclopentanoids: intermediates for the assembly of complex diterpenoids
- Creators
- Brian T BecickaFrederick L KoerwitzGary J DrtinaNorman C BaenzigerDavid F Wiemer
- Resource Type
- Journal article
- Publication Details
- Journal of organic chemistry, Vol.55(21), pp.5613-5619
- Publisher
- American Chemical Society
- DOI
- 10.1021/jo00308a020
- ISSN
- 0022-3263
- eISSN
- 1520-6904
- Language
- English
- Date published
- 10/01/1990
- Academic Unit
- Neuroscience and Pharmacology; Chemistry
- Record Identifier
- 9984216594302771
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