Journal article
Synthesis of polyethylene graft block copolymers from styrene, butyl acrylate, and butadiene
Macromolecules, Vol.35(25), pp.9246-9248
2002
DOI: 10.1021/ma020544g
Abstract
A strategy for the copolymerization of alkoxyamines with olefins; the alkoxyamine comonomers function as free-radical initiators allowing for the synthesis of graft copolymers was described. Thus, the use of polyolefins with blocks or grafts of functionalized polymers may improved adhesion to and compatibility with metals, glass, or other polymers. This paper reports on the synthesis of polyethylene graft coplymers containing low levels of grafts of functionalized homopolymers and block polymers along the backbone.
Details
- Title: Subtitle
- Synthesis of polyethylene graft block copolymers from styrene, butyl acrylate, and butadiene
- Creators
- Ned B Bowden - Center for Polymer Interfaces and Macromolecular Assemblies, Departments of Chemistry and Chemical Engineering, Stanford University, San Jose, California 95120-6099, United StatesMichaela Dankova - Center for Polymer Interfaces and Macromolecular Assemblies, Departments of Chemistry and Chemical Engineering, Stanford University, San Jose, California 95120-6099, United StatesWilly Wiyatno - Center for Polymer Interfaces and Macromolecular Assemblies, Departments of Chemistry and Chemical Engineering, Stanford University, San Jose, California 95120-6099, United StatesCraig J Hawker - IBM Almaden Research Center, 650 Harry Road, San Jose, California 95120-6099, United StatesRobert M Waymouth - Center for Polymer Interfaces and Macromolecular Assemblies, Departments of Chemistry and Chemical Engineering, Stanford University, San Jose, California 95120-6099, United States
- Resource Type
- Journal article
- Publication Details
- Macromolecules, Vol.35(25), pp.9246-9248
- Publisher
- American Chemical Society
- DOI
- 10.1021/ma020544g
- ISSN
- 0024-9297
- eISSN
- 1520-5835
- Language
- English
- Date published
- 2002
- Academic Unit
- Chemistry
- Record Identifier
- 9984216713602771
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