Journal article
Template-Controlled Reactivity in the Organic Solid State by Principles of Coordination-Driven Self-Assembly
European Journal of Inorganic Chemistry, Vol.2007(29), pp.4559-4568
10/2007
DOI: 10.1002/ejic.200700442
Abstract
In this microreview, we show how principles of coordination-driven self-assembly can be used to direct chemical reactivity in the organic solid state. We also show how products obtained from the templated solid-state reactions can be used as organic building units of metal–organic frameworks and coordination capsules. Self-assembled structures based on dinuclear ZnII and AgI complexes are used to direct stereocontrolled [2+2] photodimerizations of vinylpyridines in the solid state in up to quantitative yield. The products are used as bi- and polytopic ligands of self-assembled coordination capsules and metal–organic frameworks. We also describe emerging metal-based approaches to conduct mechanochemical reactions in organic solids. In addition to the field of supramolecular coordination chemistry, these observations impact the field of green chemistry.
Details
- Title: Subtitle
- Template-Controlled Reactivity in the Organic Solid State by Principles of Coordination-Driven Self-Assembly
- Creators
- Dejan-Krešimir Bučar - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294, USA, Fax: +1-319-335-1270Giannis S Papaefstathiou - Laboratory of Inorganic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens Panepostimiopolis, Zografou 15771, GreeceTamara D Hamilton - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294, USA, Fax: +1-319-335-1270Qianli L Chu - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294, USA, Fax: +1-319-335-1270Ivan G Georgiev - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294, USA, Fax: +1-319-335-1270Leonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294, USA, Fax: +1-319-335-1270
- Resource Type
- Journal article
- Publication Details
- European Journal of Inorganic Chemistry, Vol.2007(29), pp.4559-4568
- Publisher
- WILEY-VCH Verlag; Weinheim
- DOI
- 10.1002/ejic.200700442
- ISSN
- 1434-1948
- eISSN
- 1099-0682
- Number of pages
- 10
- Language
- English
- Date published
- 10/2007
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216583102771
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