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The aging process of naturally emitted aerosol (sea-salt and mineral aerosol) during long range transport
Journal article   Peer reviewed

The aging process of naturally emitted aerosol (sea-salt and mineral aerosol) during long range transport

Chul H Song and Gregory R Carmichael
Atmospheric environment (1994), Vol.33(14), pp.2203-2218
1999
DOI: 10.1016/S1352-2310(98)00301-X

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Abstract

The aging processes of two representative natural aerosol, sea-salt and mineral aerosol, are investigated by using a box model equipped with a thermodynamic module (SCAPE). The model is shown to successfully describe the aging processes between the gas-phase anthropogenic pollutants (SO 2, NO x , and NH 3) and primary aerosol particles, including self-neutralization process/chlorine depletion in the sea-salt aerosol; formation/dissipation of carbonate and bicarbonate ions in the mineral aerosol; irreversible dynamic deposition of SO 2 and H 2SO 4; and reversible thermodynamic distribution of inorganic volatile species. It is found that SO 2 and H 2SO 4 tend to deposit onto the mode with the largest surface area, and that ammonia deposition is controlled by preceding SO 2/H 2SO 4 deposition. During the SO 2/H 2SO 4 deposition, chloride and carbonate are continuously released from the sea-salt and mineral dust particles, respectively. The findings by the model predictions are consistent with field and observational studies.
Model Aerosol box model Mineral aerosol Sea-salt aerosol Aging process Thermodynamic

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