Journal article
The "boat" Conformation of a Resorcin[4]arene Self-assembles as a "T-shaped" Building Block in the Solid State to Form a Linear ID Hydrogen-bonded Array
Supramolecular chemistry, Vol.11(4), pp.293-299
01/01/2000
DOI: 10.1080/10610270008049141
Abstract
Co-crystallization of C-methylcalix[4]resorcinarene 1 with 4-benzylpyridine (4-bzylpy) results in the formation of a linear 1D hydrogen-bonded array, 1-4(4-bzylpy) 2, in which the boat conformation of 1, in the form of an eightfold hydrogen bond donor, serves as a "T-shaped" building block in the solid state. Crystal data for 2: triclinic, space group P1, a=14.992(1), b=16.256(1), c=16.365(1)Å, α=108.065 (1), β=96.140(1), γ=116.260(1)°, U=3258.1(3)Å
3
, Dc=1.25 g cm
−3
, Mo-Kα radiation (λ=0.71070 Å) for Z=2. Least-squares refinement based on 6045 reflections with Inet > 2.0°(Inet) (out of 8151 unique reflections) led to a final value of R = 0.048.
Details
- Title: Subtitle
- The "boat" Conformation of a Resorcin[4]arene Self-assembles as a "T-shaped" Building Block in the Solid State to Form a Linear ID Hydrogen-bonded Array
- Creators
- Leonard R Macgillivray - Steacie Institute for Molecular Sciences, National Research Council of CanadaJerry L Atwood - Department of Chemistry , University of Missouri-Columbia
- Resource Type
- Journal article
- Publication Details
- Supramolecular chemistry, Vol.11(4), pp.293-299
- Publisher
- Taylor & Francis Group
- DOI
- 10.1080/10610270008049141
- ISSN
- 1061-0278
- eISSN
- 1029-0478
- Language
- English
- Date published
- 01/01/2000
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216696802771
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