Journal article
The cycloaddition of diethyl chlorophosphite with norbornadiene: Synthesis and crystal structure of the cycloadduct
Journal of heterocyclic chemistry, Vol.33(3), pp.979-981
05/1996
DOI: 10.1002/jhet.5570330369
Abstract
In the presence of Lewis acids, diethyl phosphorochloridite reacts with norbornadiene to afford the tetracyclic phosphinate ester 3. The reaction is believed to involve formation of phosphenium ions stabilized only by alkoxy substituent. The cycloadduct of the reaction was characterized by its spectral data, by single crystal diffraction analysis of the parent acid, and 31P and 27Al nmr experiments.
Details
- Title: Subtitle
- The cycloaddition of diethyl chlorophosphite with norbornadiene: Synthesis and crystal structure of the cycloadduct
- Creators
- Vassilios Roussis - Department of Pharmacy, Division of Pharmacognosy, University of Athens, Panepistimiopolis Zografou, GR-157 71, Athens, GreeceNorman C Bænziger - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USADavid F Wiemer - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA
- Resource Type
- Journal article
- Publication Details
- Journal of heterocyclic chemistry, Vol.33(3), pp.979-981
- Publisher
- Wiley-Blackwell
- DOI
- 10.1002/jhet.5570330369
- ISSN
- 0022-152X
- eISSN
- 1943-5193
- Number of pages
- 3
- Language
- English
- Date published
- 05/1996
- Academic Unit
- Neuroscience and Pharmacology; Chemistry
- Record Identifier
- 9984216570802771
Metrics
4 Record Views