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The reaction of vinyl phosphates with iodotrimethylsilane: Synthesis of vinyl iodides from ketones
Journal article   Peer reviewed

The reaction of vinyl phosphates with iodotrimethylsilane: Synthesis of vinyl iodides from ketones

Koo Lee and David F Wiemer
Tetrahedron letters, Vol.34(15), pp.2433-2436
1993
DOI: 10.1016/S0040-4039(00)60434-3

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Abstract

A new method for preparation of vinyl iodides from ketones is described, based on the reaction of vinyl phosphates with iodotrimethylsilane. A new method for preparation of vinyl iodides from ketones is described, based on reaction of vinyl phosphates with three equivalents of TMSI or TMSCI-NaI.

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