Journal article
The synthesis of 1-thia-6-oxa-6a lambda(4)-seleno-3-azapentalene and a 3H-1,2,4-dithiazole
Organic & biomolecular chemistry, Vol.5(4), pp.613-616
01/01/2007
DOI: 10.1039/b617097h
PMID: 17285169
Abstract
The reaction of thiocarbamoyl isoselenocyanate with a carbanion gave 1-thia-6-oxa-6a lambda(4)-seleno-3-azapentalene, which has a hypervalent selenium, as the major product. The by-products 3-diacylmethylidene-5-dimethylamino-3H-1,2,4-dithiazole and thiocarbamate thioanhydride were also formed.
Details
- Title: Subtitle
- The synthesis of 1-thia-6-oxa-6a lambda(4)-seleno-3-azapentalene and a 3H-1,2,4-dithiazole
- Creators
- Mamoru Koketsu - Gifu UniversityToshihiro Otsuka - Gifu UniversityDale Swenson - University of IowaHideharu Ishihara - Gifu University
- Resource Type
- Journal article
- Publication Details
- Organic & biomolecular chemistry, Vol.5(4), pp.613-616
- Publisher
- Royal Soc Chemistry
- DOI
- 10.1039/b617097h
- PMID
- 17285169
- ISSN
- 1477-0520
- eISSN
- 1477-0539
- Number of pages
- 4
- Language
- English
- Date published
- 01/01/2007
- Academic Unit
- Chemistry
- Record Identifier
- 9984622745602771
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