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Total synthesis of ( R, R, R)- and ( S, S, S)-schweinfurthin F: Differences of bioactivity in the enantiomeric series
Journal article   Peer reviewed

Total synthesis of ( R, R, R)- and ( S, S, S)-schweinfurthin F: Differences of bioactivity in the enantiomeric series

Nolan R Mente, Andrew J Wiemer, Jeffrey D Neighbors, John A Beutler, Raymond J Hohl and David F Wiemer
Bioorganic & medicinal chemistry letters, Vol.17(4), pp.911-915
2007
DOI: 10.1016/j.bmcl.2006.11.096
PMID: 17236766

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Abstract

Total synthesis of the ( R, R, R)- and ( S, S, S)-enantiomers of the natural product schweinfurthin F has been completed. Comparisons of spectral data and optical rotations with those reported for the natural product, as well as a variety of bioassay data, allow assignment of the natural material as the ( R, R, R)-isomer.
Schweinfurthin Activity Synthesis Enantiomer

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