Journal article
Two act as one: unexpected dimers of catechol direct a solid-state [2+2] photodimerization in a six-component hydrogen-bonded assembly
Chemical communications (Cambridge, England), Vol.50(100), pp.15960-15962
12/28/2014
DOI: 10.1039/c4cc07747d
PMID: 25383606
Abstract
We describe hydrogen-bonded dimers of catechol that act collectively as a single template to direct an intermolecular [2+2] photocycloaddition in the solid state. The directed reactivity involves discrete, six-component hydrogen-bonded assemblies and a photoreaction that occurs stereoselectively and in quantitative yield.
Details
- Title: Subtitle
- Two act as one: unexpected dimers of catechol direct a solid-state [2+2] photodimerization in a six-component hydrogen-bonded assembly
- Creators
- Giannis S PapaefstathiouAndrew J E DuncanLeonard R MacGillivray
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.50(100), pp.15960-15962
- DOI
- 10.1039/c4cc07747d
- PMID
- 25383606
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Grant note
- DOI: 10.13039/100000078, name: Division of Materials Research, award: 1408834
- Language
- English
- Date published
- 12/28/2014
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216591302771
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