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Unusually high soil nitrogen oxide emissions influence air quality in a high-temperature agricultural region
Journal article   Open access   Peer reviewed

Unusually high soil nitrogen oxide emissions influence air quality in a high-temperature agricultural region

P Y Oikawa, C Ge, J Wang, J R Eberwein, L L Liang, L A Allsman, D A Grantz and G D Jenerette
Nature communications, Vol.6(1), pp.8753-8753
11/10/2015
DOI: 10.1038/ncomms9753
PMCID: PMC4659929
PMID: 26556236
url
https://doi.org/10.1038/ncomms9753View
Published (Version of record) Open Access

Abstract

Fertilized soils have large potential for production of soil nitrogen oxide (NOx=NO+NO2), however these emissions are difficult to predict in high-temperature environments. Understanding these emissions may improve air quality modelling as NOx contributes to formation of tropospheric ozone (O3), a powerful air pollutant. Here we identify the environmental and management factors that regulate soil NOx emissions in a high-temperature agricultural region of California. We also investigate whether soil NOx emissions are capable of influencing regional air quality. We report some of the highest soil NOx emissions ever observed. Emissions vary nonlinearly with fertilization, temperature and soil moisture. We find that a regional air chemistry model often underestimates soil NOx emissions and NOx at the surface and in the troposphere. Adjusting the model to match NOx observations leads to elevated tropospheric O3. Our results suggest management can greatly reduce soil NOx emissions, thereby improving air quality.
Nitrogen - chemistry Nitrogen Oxides - chemistry Soil - chemistry Fertilizers - analysis Sorghum Air Pollution - analysis California Hot Temperature Air Pollutants - chemistry

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